水合双（1-甲基-1H-咪唑-κN）双（硝酸根-κO）铜（II）
Aqua-bis-(1-methyl-1H-imidazole-κN)bis-(nitrato-κO)copper(II).
作者信息
Zhu Run-Qiang
机构信息
Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 24;66(Pt 12):m1628. doi: 10.1107/S1600536810047525.
Abstract
The title complex mol-ecule, [Cu(NO(3))(2)(C(4)H(6)N(2))(2)(H(2)O)], has crystallographically imposed twofold symmetry. The Cu(II) atom displays a distorted square-pyramidal CuN(2)O(3) coordination geometry. In the crystal, inter-molecular O-H⋯O hydrogen bonds between the coordinated water mol-ecule and the nitrate anions form chains parallel to the c axis.
摘要
标题配合物分子[Cu(NO₃)₂(C₄H₆N₂)₂(H₂O)]具有晶体学上的二重对称性。Cu(II)原子呈现出扭曲的四方锥CuN₂O₃配位几何构型。在晶体中，配位水分子与硝酸根阴离子之间的分子间O—H⋯O氢键形成平行于c轴的链。
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