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三[2-(丙基亚氨基甲基)苯酚根-κN,O]铁(III)

Tris[2-(propyl-imino-meth-yl)phenolato-κN,O]iron(III).

作者信息

Hao Lujiang, Mu Chunhua, Kong Binbin

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 25;64(Pt 7):m955. doi: 10.1107/S1600536808018540.

DOI:10.1107/S1600536808018540
PMID:21202804
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961833/
Abstract

The title compound, [Fe(C(10)H(12)NO)(3)], is isostructural with its Co(III)-containing analogue. The Fe(III) cation is chelated by three Schiff base ligands via three N and three O atoms, and exhibits a slightly distorted octa-hedral geometry. The longest Fe-O and Fe-N bonds lie trans to each other and may be regarded as axial bonds, while the equatorial plane contains two mutually trans O and two trans N atoms.

摘要

标题化合物[Fe(C₁₀H₁₂NO)₃]与其含Co(III)的类似物同构。Fe(III)阳离子通过三个N原子和三个O原子被三个席夫碱配体螯合，呈现出略微扭曲的八面体几何构型。最长的Fe - O键和Fe - N键彼此相对，可视为轴向键，而赤道平面包含两个相互相对的O原子和两个相对的N原子。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b21a/2961833/2919fa14fe30/e-64-0m955-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b21a/2961833/2919fa14fe30/e-64-0m955-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b21a/2961833/2919fa14fe30/e-64-0m955-fig1.jpg

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