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三[4-溴-2-(甲基亚氨基甲基)苯酚根-κ(2)N,O]钴(III)

Tris[4-bromo-2-(methyl-imino-meth-yl)phenolato-κ(2) N,O]cobalt(III).

作者信息

Huang Qiu-Ping, Zhang Chun-Lian, Zhao Ru-Xia, Yang Li, Jiang Xi-Fu

机构信息

College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 16;69(Pt 11):m601. doi: 10.1107/S1600536813027591.

DOI:10.1107/S1600536813027591
PMID:24454033
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3884257/
Abstract

In the title compound, [Co(C8H7BrNO)3], the Co(III) ion is coordinated in a slightly distorted octa-hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl-imino-meth-yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2) and 62.9 (2)°. In the crystal, mol-ecules are linked by pairs of weak C-H⋯Br hydrogen bonds, forming inversion dimers.

摘要

在标题化合物[Co(C₈H₇BrNO)₃]中，Co(III)离子由来自三个双齿4-溴-2-(甲基亚氨基甲基)苯酚配体的三个N原子和三个O原子在略微扭曲的八面体环境中配位。苯环之间的二面角分别为82.6 (2)°、57.1 (2)°和62.9 (2)°。在晶体中，分子通过成对的弱C-H⋯Br氢键相连，形成反演二聚体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ec/3884257/1598c59d3a93/e-69-0m601-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ec/3884257/84738e787094/e-69-0m601-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ec/3884257/1598c59d3a93/e-69-0m601-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ec/3884257/84738e787094/e-69-0m601-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ec/3884257/1598c59d3a93/e-69-0m601-fig2.jpg

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