链状聚[[三（吡啶-κN）铜（II）]-μ-四氟对苯二甲酸根-κO:O]
catena-Poly[[tris-(pyridine-κN)copper(II)]-μ-tetra-fluoro-terephthalato-κO:O].
作者信息
Zheng Chang-Ge, Zhang Jie, Hong Jian-Quan, Li Song
机构信息
School of Chemical and Materials Engineering, Jiangnan University, 1800 Lihu Road, Wuxi, Jiangsu 214122, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 28;64(Pt 7):m965. doi: 10.1107/S1600536808018977.
In the title compound, Cu(C(8)F(4)O(4))(C(5)H(5)N)(3), the Cu(II) atom, lying on a twofold rotation axis, is five-coordinated by two O atoms from two tetra-fluoro-terephthalate ligands and three N atoms from three pyridine ligands in a distorted trigonal-bipyramidal geometry. Adjacent Cu(II) atoms are connected via the bridging tetra-fluoro-terephthalate ligands into a one-dimensional chain running along the [101] direction.
在标题化合物[Cu(C₈F₄O₄)(C₅H₅N)₃]ₙ中，位于二重旋转轴上的Cu(II)原子由来自两个四氟对苯二甲酸酯配体的两个O原子和来自三个吡啶配体的三个N原子以扭曲的三角双锥几何构型进行五配位。相邻的Cu(II)原子通过桥连的四氟对苯二甲酸酯配体连接成沿[101]方向延伸的一维链。
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