链状聚[[双（吡啶-κN）锌（II）]-μ-苯-1,4-二甲酸根-κO:O]
catena-Poly[[bis-(pyridine-κN)zinc(II)]-μ-benzene-1,4-dicarboxyl-ato-κO:O].
作者信息
Wang Li-Fen, Li Chuan-Qiang, Qiu Wen-Ge, He Hong
机构信息
College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 23;66(Pt 7):m829. doi: 10.1107/S1600536810022385.
In the title coordination polymer, Zn(C(8)H(4)O(4))(C(5)H(5)N)(2), the Zn(II) atom, located on a twofold rotation axis, is tetra-coordinated by two monodentate O atoms from two different carboxyl-ate groups and two pyridyl N atoms, forming a distorted tetra-hedral geometry. The Zn(II) atoms are bridged by terephthalate ligands, generating an infinite zigzag chain along [101].
在标题配位聚合物[Zn(C₈H₄O₄)(C₅H₅N)₂]ₙ中，位于二重旋转轴上的Zn(II)原子由来自两个不同羧酸根基团的两个单齿O原子和两个吡啶基N原子进行四配位，形成扭曲的四面体几何构型。Zn(II)原子由对苯二甲酸酯配体桥连，沿[101]方向生成无限之字形链。
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