双（O，O'-二苯乙基二硫代磷酸根合-κS，S'）双（4-甲基吡啶-κN）镍（II）
Bis(O,O'-diphenethyl dithio-phosphato-κS,S')bis-(4-methyl-pyridine-κN)nickel(II).
作者信息
Feng Jian-Shen, Cheng Yu, Zou Li-Ke, Xie Bin, Zhang Xiu-Lan
机构信息
College of Chemistry and Pharmaceutical Engineering, Sichuan University of Science & Engineering, Zigong, Sichuan 643000, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 12;64(Pt 8):m1022. doi: 10.1107/S1600536808020898.
The title complex, [Ni(C(16)H(18)O(2)PS(2))(2)(C(6)H(7)N)(2)], exhibits a roughly octa-hedral coordination geometry. The Ni(II) atom lies on an inversion centre and is coordinated by four S atoms of O,O'-diphenethyl dithio-phosphate mol-ecules and two N atoms of 4-methyl-pyridine mol-ecules. Important geometric data include Ni-N = 2.100 (3) Å, and Ni-S = 2.5101 (10) and 2.4772 (11) Å.
标题配合物[Ni(C₁₆H₁₈O₂PS₂)₂(C₆H₇N)₂]呈现出大致八面体的配位几何构型。Ni(II)原子位于一个对称中心上，由O,O'-二苯乙基二硫代磷酸分子的四个S原子和4-甲基吡啶分子的两个N原子配位。重要的几何数据包括Ni-N = 2.100 (3) Å，以及Ni-S = 2.5101 (10) 和2.4772 (11) Å。
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