链状聚[[[双-(O,O'-二异丁基二硫代磷酸根-κS,S')镍(II)]-μ-1,2-双-(4-吡啶基亚甲基)肼-κN:N']甲苯溶剂合物]
catena-Poly[[[bis-(O,O'-diisobutyl dithio-phosphato-κS,S')nickel(II)]-μ-1,2-bis-(4-pyridylmethyl-ene)hydrazine-κN:N'] toluene disolvate].
作者信息
Berdugo Erick, Tiekink Edward R T
机构信息
Department of Chemistry, The University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 13;64(Pt 7):m911. doi: 10.1107/S1600536808017121.
The polymeric title compound, {[Ni(C(8)H(18)O(2)PS(2))(2)(C(12)H(10)N(4))]·2C(7)H(7)}(n), has a linear topology and features octa-hedrally coordinated Ni atoms with a trans-N(2)S(4) donor set. The toluene solvent mol-ecules occupy channels defined by the three-dimensional stacking of the polymeric chains. The Ni atom is located at a centre of inversion and the bridging 1,2-bis-(4-pyridylmethyl-ene)hydrazine4-pyridine mol-ecule is also disposed about a centre of inversion. One isobutoxy group is disordered equally over two positions.
聚合标题化合物{[Ni(C₈H₁₈O₂PS₂)₂(C₁₂H₁₀N₄)]·2C₇H₇}ₙ具有线性拓扑结构，其特征是八面体配位的Ni原子，配体为反式-N₂S₄供体组合。甲苯溶剂分子占据由聚合物链的三维堆积所定义的通道。Ni原子位于对称中心，桥连的1,2-双(4-吡啶基亚甲基)肼基-4-吡啶分子也围绕对称中心排列。一个异丁氧基在两个位置上无序分布，占有率相等。
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