• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

{N,N'-双[(E)-3-苯基-丙-2-烯-1-基亚基]丙烷-1,3-二胺-κN,N']二氯化钴(II)

{N,N'-Bis[(E)-3-phenyl-prop-2-en-1-yl-idene]propane-1,3-diamine-κN,N']dichloridocobalt(II).

作者信息

Montazerozohori Morteza, Habibi Mohammad Hossein, Amirnasr Mehdi, Ariyoshi Keita, Suzuki Takayoshi

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):m617. doi: 10.1107/S1600536809016274.

DOI:10.1107/S1600536809016274
PMID:21582987
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969584/
Abstract

The Co(II) atom in the title monomeric Schiff base complex, [CoCl(2)(C(21)H(22)N(2))], is bonded to two Cl atoms and to two N atoms of the Schiff base ligand N,N'-bis-[(E)-3-phenyl-prop-2-en-1-yl-idene]propane-1,3-diamine in a distorted tetra-hedral geometry. The mol-ecule has an idealised mirror symmetry, but is not located on a crystallographic mirror plane.

摘要

在标题单体席夫碱配合物[CoCl₂(C₂₁H₂₂N₂)]中，钴(II)原子与两个氯原子以及席夫碱配体N,N'-双-[(E)-3-苯基-丙-2-烯-1-基亚甲基]丙烷-1,3-二胺的两个氮原子相连，呈扭曲的四面体几何构型。该分子具有理想的镜像对称性，但并不位于晶体学镜面平面上。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc1/2969584/c9be40f394a1/e-65-0m617-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc1/2969584/c9be40f394a1/e-65-0m617-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc1/2969584/c9be40f394a1/e-65-0m617-fig1.jpg

相似文献

1
{N,N'-Bis[(E)-3-phenyl-prop-2-en-1-yl-idene]propane-1,3-diamine-κN,N']dichloridocobalt(II).{N,N'-双[(E)-3-苯基-丙-2-烯-1-基亚基]丙烷-1,3-二胺-κN,N']二氯化钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):m617. doi: 10.1107/S1600536809016274.
2
[Bis(3-phenyl-prop-2-enyl-idene)propane-1,3-diamine-κN,N']dibromidocobalt(II).[双(3-苯基-丙-2-烯基亚甲基)丙烷-1,3-二胺-κN,N']二溴化钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 13;65(Pt 1):m56. doi: 10.1107/S1600536808041408.
3
{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N'',N'''}bis-(thio-cyanato-κN)manganese(II).{N,N'-双[1-(2-吡啶基)亚乙基]乙烷-1,2-二胺-κN,N',N'',N'''}双(硫氰酸根合-κN)锰(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m776. doi: 10.1107/S1600536810021550.
4
{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]propane-1,2-diamine-κN,N',N'',N'''}bis-(thio-cyanato-κN)manganese(II).{N,N'-双[1-(2-吡啶基)亚乙基]丙烷-1,2-二胺-κN,N',N'',N'''}双(硫氰酸根合-κN)锰(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m777. doi: 10.1107/S1600536810021549.
5
{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]propane-1,2-diamine}-bis(thio-cyanato-κN)-nickel(II).
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 31;66(Pt 8):m1033. doi: 10.1107/S1600536810029454.
6
{(1R,2R)-N,N'-Bis[2-(N-methyl-anilino)benzyl-idene]cyclo-hexane-1,2-diamine-κN,N'}dichloridoiron(II).{(1R,2R)-N,N'-双[2-(N-甲基苯胺基)亚苄基]环己烷-1,2-二胺-κN,N'}二氯化铁(II)
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):m64. doi: 10.1107/S1600536811053773. Epub 2011 Dec 17.
7
[N,N'-Bis(2,6-dichloro-benzyl-idene)propane-1,3-diamine-κ(2)N,N']dibromidozinc.[二（2,6 - 二氯亚苄基）丙烷 - 1,3 - 二胺 - κ(2)N,N']二溴化锌
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m971. doi: 10.1107/S1600536812027997. Epub 2012 Jun 23.
8
{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N'',N'''}(thio-cyanato-κN)zinc(II) perchlorate.高氯酸{N,N'-双[1-(2-吡啶基)亚乙基]乙烷-1,2-二胺-κN,N',N'',N'''}（硫氰酸根-κN）锌（II）
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m778-9. doi: 10.1107/S1600536810021628.
9
(2-{[1-(Pyridin-2-yl)ethyl-idene]amino-meth-yl}pyridine-κN,N',N'')bis-(thio-cyanato-κN)zinc.（2-{[1-（吡啶-2-基）亚乙基]氨基甲基}吡啶-κN，N′，N″）双（硫氰酸根合-κN）锌
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1616. doi: 10.1107/S1600536811043984. Epub 2011 Oct 29.
10
{N,N'-Bis[(E)-3-phenyl-allyl-idene]ethane-1,2-diamine}dichloridozinc(II).{N,N'-双[(E)-3-苯基-烯丙叉基]乙烷-1,2-二胺}二氯锌(II)
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):m1597. doi: 10.1107/S1600536808037860.

引用本文的文献

1
catena-Poly[[{2-[(2-hy-droxy-eth-yl)imino-meth-yl]-6-meth-oxy-phenolato}copper(II)]-μ-thio-cyanato].链状聚[[{2-[(2-羟乙基)亚氨基甲基]-6-甲氧基苯酚根合}铜(II)]-μ-硫氰酸根]
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 28;66(Pt 9):m1172-3. doi: 10.1107/S1600536810034021.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.