Qu Zhi-Rong, Li Xiu-Zhi
Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 31;64(Pt 8):m1085. doi: 10.1107/S1600536808023179.
The title compound, CdCl(2)(C(9)H(11)NO(2)), is a coordination polymer prepared by the hydro-thermal reaction of cadmium(II) chloride and 3-amino-3-phenyl-propanoic acid. Geometric parameters are in the usual ranges. The cadmium cation is octa-hedrally coordinated by four Cl atoms at equatorial sites and two O atoms from two ligands at the axial sites. The material is composed of one-dimensional extended polymeric chains in which two Cl atoms bridge Cd atoms. The crystal structure is stabilized by an intra-molecular N-H⋯O hydrogen bond.
标题化合物[CdCl₂(C₉H₁₁NO₂)]ₙ是通过氯化镉(II)与3-氨基-3-苯基丙酸的水热反应制备的一种配位聚合物。几何参数在常见范围内。镉阳离子在赤道平面由四个Cl原子八面体配位，在轴向由来自两个配体的两个O原子配位。该材料由一维延伸的聚合物链组成，其中两个Cl原子桥连Cd原子。晶体结构通过分子内N—H⋯O氢键得以稳定。
