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链状聚[镉（II）-μ-苯-1,2-二胺-κN:N'-二-μ-氯]

catena-Poly[cadmium(II)-μ-benzene-1,2-diamine-κN:N'-di-μ-chlorido].

作者信息

Liang Wen-Xian, Qu Zhi-Rong

机构信息

Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 6;64(Pt 10):m1254. doi: 10.1107/S1600536808027980.

DOI:10.1107/S1600536808027980
PMID:21201010
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959288/
Abstract

The title compound, CdCl(2)(C(6)H(8)N(2)), is a coordination polymer prepared by the hydro-thermal reaction of cadmium chloride and o-diamino-benzene. The cadmium cation, located on an inversion center, is octa-hedrally coordinated by four Cl atoms at equatorial sites and two N atoms from two ligands at the axial sites. Cd atoms are bridged by Cl atoms, forming extended chains parallel to [010]. Neighboring chains are connected by N-H⋯Cl hydrogen bonds.

摘要

标题化合物[CdCl₂(C₆H₈N₂)]ₙ是通过氯化镉与邻二氨基苯的水热反应制备的一种配位聚合物。位于对称中心的镉阳离子在赤道平面由四个氯原子八面体配位，在轴向由来自两个配体的两个氮原子配位。镉原子由氯原子桥连，形成平行于[010]的延伸链。相邻的链通过N—H⋯Cl氢键相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1470/2959288/c566b78995d1/e-64-m1254-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1470/2959288/5e037d7440bb/e-64-m1254-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1470/2959288/c566b78995d1/e-64-m1254-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1470/2959288/5e037d7440bb/e-64-m1254-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1470/2959288/c566b78995d1/e-64-m1254-fig2.jpg

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