Huang Miao-Ling, Xie Qing-Fan, Xian Jing-Chun, Chen Yan-Min, Zhou Zi-Qiao
Department of Chemistry and Science of life, Quanzhou Normal University, Fujian 362000, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 31;64(Pt 8):m1086. doi: 10.1107/S1600536808023647.
The title complex, [Cu(2)(C(7)H(6)NO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2C(7)H(7)NO(2)·2H(2)O, consists of a dinuclear Cu(2)(C(7)H(6)NO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(2) cation, two Cl(-) anions, two 4-amino-benzoic acid mol-ecules and two disordered water mol-ecules (site occupancy factors 0.5). The Cu(II) ion adopts a distorted square-pyramidal geometry formed by two N atoms from the 1,10-phenanthroline ligand and two O atoms of the two 4-amino-benzoic acid ligands and one water O atom. The Cu⋯Cu separation is 3.109 (2) Å. A twofold axis passes through the mid-point of the Cu⋯Cu vector.
标题配合物[Cu₂(C₇H₆NO₂)₂(C₁₂H₈N₂)₂(H₂O)₂]·2C₇H₇NO₂·2H₂O由一个双核[Cu₂(C₇H₆NO₂)₂(C₁₂H₈N₂)₂(H₂O)₂]²⁺阳离子、两个Cl⁻阴离子、两个4-氨基苯甲酸分子和两个无序水分子（占据因子0.5）组成。Cu(II)离子采用扭曲的四方锥几何构型，由1,10-菲咯啉配体的两个N原子、两个4-氨基苯甲酸配体的两个O原子和一个水O原子构成。Cu⋯Cu间距为3.109 (2) Å。一个二重轴通过Cu⋯Cu向量的中点。
