微波辅助芳基溴化物在金属有机骨架上的直接氰化反应。
Microwave-assisted cyanation of an aryl bromide directly on a metal-organic framework.
机构信息
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, USA.
出版信息
Inorg Chem. 2011 Feb 7;50(3):729-31. doi: 10.1021/ic102436b. Epub 2011 Jan 5.
Abstract
A microwave-assisted postsynthetic modification (PSM) reaction on a metal-organic framework (MOF) has been realized. Cyanation of the Zr(4+)-based UiO-66-Br was achieved with CuCN and microwave irradiation to produce UiO-66-CN. This protocol represents a notable example of PSM on an aryl halide MOF producing a cyano-functionalized MOF.
摘要
一种在金属有机骨架（MOF）上进行的微波辅助后合成修饰（PSM）反应已经实现。通过 CuCN 和微波辐射对基于 Zr(4+)的 UiO-66-Br 进行氰化，生成 UiO-66-CN。该方案代表了在芳基卤化物 MOF 上进行 PSM，生成氰基功能化 MOF 的显著实例。
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2
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