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通过调节剂和温度控制互穿金属有机骨架的穿透程度及其对氢气的吸附性能。

Controlling the shifting degree of interpenetrated metal-organic frameworks by modulator and temperature and their hydrogen adsorption properties.

机构信息

State Key Laboratory of Coordination Chemistry, Department of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China.

出版信息

Chem Commun (Camb). 2011 Mar 7;47(9):2556-8. doi: 10.1039/c0cc04146g. Epub 2011 Jan 6.

Abstract

For the first time, the shifting degree of pcu-type interpenetrated framework was well controlled by employing a modulator and changing the temperature, in which their evacuated samples are almost non-crystalline products with different meso- and microstructures, resulting in different hydrogen adsorption properties.

摘要

首次通过使用调节剂并改变温度来很好地控制 pcu 型互穿骨架的转变程度,其中抽真空后的样品几乎是具有不同介观和微观结构的无定形产物,导致其具有不同的吸附性能。

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