Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996, USA.
Phys Rev Lett. 2010 Nov 12;105(20):205502. doi: 10.1103/PhysRevLett.105.205502. Epub 2010 Nov 11.
When a stress is applied on a metallic glass it deforms following Hook's law. Therefore it may appear obvious that a metallic glass deforms elastically. Using x-ray diffraction and anisotropic pair-density function analysis we show that only about 3/4 in volume fraction of metallic glasses deforms elastically, whereas the rest of the volume is anelastic and in the experimental time scale deform without resistance. We suggest that this anelastic portion represents residual liquidity in the glassy state. Many theories, such as the free-volume theory, assume the density of defects in the glassy state to be of the order of 1%, but this result shows that it is as much as a quarter.
当施加在金属玻璃上的应力遵循胡克定律时,它会发生变形。因此,金属玻璃弹性变形似乎是显而易见的。通过 X 射线衍射和各向异性对密度函数分析,我们表明只有大约 3/4 的金属玻璃体积分数发生弹性变形,而其余部分是非弹性的,在实验时间尺度内无阻力地变形。我们认为,这部分非弹性部分代表玻璃态下的残余流动性。许多理论,如自由体积理论,假设玻璃态下缺陷的密度在 1%左右,但这一结果表明,其密度高达四分之一。