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铅锆钛酸单晶体中菱形和单斜有序的竞争研究。

Single crystal study of competing rhombohedral and monoclinic order in lead zirconate titanate.

机构信息

NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA.

出版信息

Phys Rev Lett. 2010 Nov 12;105(20):207601. doi: 10.1103/PhysRevLett.105.207601. Epub 2010 Nov 8.

DOI:10.1103/PhysRevLett.105.207601
PMID:21231265
Abstract

Neutron diffraction data obtained on single crystals of PbZr(1-x)Ti(x)O3 with x=0.325 and x=0.460, which lie on the pseudorhombohedral side of the morphotropic phase boundary, suggest a coexistence of rhombohedral (R3m/R3c) and monoclinic (Cm) domains and that monoclinic order is enhanced by Ti substitution. A monoclinic phase with a doubled unit cell (Cc) is ruled out as the ground state.

摘要

对位于准同型相界伪菱面体侧的 PbZr(1-x)Ti(x)O3 单晶体(x=0.325 和 x=0.460)进行的中子衍射实验表明,存在菱面体(R3m/R3c)和单斜(Cm)畴的共存,并且 Ti 取代增强了单斜有序。排除了具有两倍单元胞(Cc)的单斜相作为基态。

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