NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA.
Phys Rev Lett. 2010 Nov 12;105(20):207601. doi: 10.1103/PhysRevLett.105.207601. Epub 2010 Nov 8.
Neutron diffraction data obtained on single crystals of PbZr(1-x)Ti(x)O3 with x=0.325 and x=0.460, which lie on the pseudorhombohedral side of the morphotropic phase boundary, suggest a coexistence of rhombohedral (R3m/R3c) and monoclinic (Cm) domains and that monoclinic order is enhanced by Ti substitution. A monoclinic phase with a doubled unit cell (Cc) is ruled out as the ground state.
对位于准同型相界伪菱面体侧的 PbZr(1-x)Ti(x)O3 单晶体(x=0.325 和 x=0.460)进行的中子衍射实验表明,存在菱面体(R3m/R3c)和单斜(Cm)畴的共存,并且 Ti 取代增强了单斜有序。排除了具有两倍单元胞(Cc)的单斜相作为基态。