通过内环 N-酰亚胺离子环化反应合成（二）苯并氮杂环酮。
A novel synthesis of (di)-benzazocinones via an endocyclic N-acyliminium ion cyclisation.
机构信息
Department of Chemistry, University College London, 20 Gordon Street, London, UK WC1H 0AJ.
出版信息
Org Biomol Chem. 2011 Mar 7;9(5):1547-54. doi: 10.1039/c0ob00559b. Epub 2011 Jan 13.
PMID:21234463
Abstract
The triflic acid-mediated endocyclic N-acyliminium ion cyclisation provides a facile synthesis of (di)-benzazocinones. On reduction of the 10-phenyl derivative, an unusually non-polar tertiary alkylamine was obtained.
摘要
三氟乙酸介导的中环 N-酰亚胺离子环化反应为（二）苯并氮杂环酮的简便合成提供了条件。还原 10-苯基衍生物时，得到了一种异常非极性的叔烷基胺。
Zotero 插件