酸催化合成双环[3.n.1]烯二酮。
Acid-catalyzed synthesis of bicyclo[3.n.1]alkenediones.
机构信息
Department of Chemistry, Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford OX1 3TA, UK.
出版信息
Org Lett. 2011 Feb 18;13(4):664-7. doi: 10.1021/ol102909t. Epub 2011 Jan 19.
PMID:21247086
Abstract
An acid-catalyzed Dieckmann-type reaction has been developed to access functionalized bicyclo[3.2.1]alkenediones. This methodology has been successfully extended to more substituted and larger ring homologues, providing a new and efficient route to the core of numerous attractive natural products and their analogues.
摘要
发展了一种酸催化的 Dieckmann 型反应来构建官能化的双环[3.2.1]烯酮。该方法已成功扩展到更多取代和更大环同系物，为许多有吸引力的天然产物及其类似物的核心提供了一种新的有效途径。
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