非共价钌多吡啶配合物-碳纳米管复合材料：在溶液中功能溶解碳纳米管的一种替代方法。
Non-covalent ruthenium polypyridyl complexes-carbon nanotubes composites: an alternative for functional dissolution of carbon nanotubes in solution.
机构信息
Department of Chemistry, MS-60, Rice University, 6100 S. Main Street, Houston, TX 77005, USA.
出版信息
Chem Commun (Camb). 2011 Feb 28;47(8):2246-8. doi: 10.1039/c0cc05295g. Epub 2011 Jan 24.
PMID:21258735
Abstract
The dispersion of single-walled carbon nanotubes (SWCNTs) in the presence of water soluble polypyridyl complexes of the general formula Ru(x)(bpy)(y)L (L = dppz, dppn, tpphz) is reported. These ligands have extended planar π systems, which aid in the solubilization of SWCNTs via π-π interactions.
摘要
报道了在水溶性多吡啶配合物Ru(x)(bpy)(y)L（L = dppz、dppn、tpphz）存在下的单壁碳纳米管（SWCNTs）的分散情况。这些配体具有扩展的平面π体系，通过π-π相互作用有助于 SWCNTs 的溶解。
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