相转移条件下异噁唑啉-N-氧化物的催化不对称合成。
Catalytic asymmetric syntheses of isoxazoline-N-oxides under phase-transfer conditions.
机构信息
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.
出版信息
Chem Commun (Camb). 2011 Apr 21;47(15):4358-60. doi: 10.1039/c0cc05786j. Epub 2011 Feb 1.
PMID:21286641
Abstract
Catalytic asymmetric syntheses of various isoxazoline-N-oxides have been accomplished by asymmetric phase-transfer conjugate addition of bromomalonate to nitroolefins and subsequent ring-closing O-alkylation.
摘要
通过不对称相转移共轭加成溴代丙二酸酯与硝基烯烃，随后进行闭环 O-烷基化反应，实现了各种异恶唑啉-N-氧化物的催化不对称合成。
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