手性改性 2-硼基丁二烯的新型烯丙基转移反应：手性偕二烯丙基醇的合成。
A novel allylic transfer reaction of chirally modified 2-borylbutadiene: synthesis of chiral homoallenyl alcohols.
机构信息
BK-21 School of Chemical Materials Science and Department of Chemistry, Sungkyunkwan University, Suwon 440-746, Korea.
出版信息
Chem Commun (Camb). 2011 Apr 7;47(13):3811-3. doi: 10.1039/c0cc05751g. Epub 2011 Feb 14.
PMID:21321709
Abstract
An enantioselective synthesis of the homoallenyl alcohols was achieved from the reaction of chiral 2-borylbutadiene with aldehydes through an allylic transfer reaction in good yields and enantioselectivities.
摘要
通过手性 2-硼基丁二烯与醛的烯丙基转移反应，以良好的收率和对映选择性实现了同型烯丙基醇的对映选择性合成。
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