石墨和石墨烯的 Diels-Alder 化学：石墨烯作为二烯和亲二烯体。
Diels-Alder chemistry of graphite and graphene: graphene as diene and dienophile.
机构信息
Center for Nanoscale Science and Engineering, Department of Chemistry, University of California, Riverside, California 92521-0403, United States.
出版信息
J Am Chem Soc. 2011 Mar 16;133(10):3324-7. doi: 10.1021/ja200118b. Epub 2011 Feb 22.
PMID:21341649
Abstract
The zero-band-gap electronic structure of graphene enables it to function as either the diene or the dienophile in the Diels-Alder reaction, and this versatile synthetic method offers a powerful strategy for the reversible modification of the electronic properties of graphene under very mild conditions.
摘要
石墨烯的零带隙电子结构使其能够在 Diels-Alder 反应中充当双烯或亲双烯体，这种多功能的合成方法为在非常温和的条件下可逆修饰石墨烯的电子性质提供了一种强大的策略。
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