Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208 016, India.
Dalton Trans. 2011 May 28;40(20):5394-418. doi: 10.1039/c0dt01069c. Epub 2011 Mar 3.
Molecular transition-metal phosphonates are of relatively recent origin and can be assembled by several synthetic strategies. The nuclearity and the structure of the metal aggregates can be modulated by several factors including the stoichiometry of the reactants, nature of the metal precursor and the type of phosphonic acid used. This perspective summarizes some of the recent work carried out on copper(II)-, zinc(II)- and cadmium(II) phosphonates with particular emphasis on their synthesis and structure.
分子过渡金属膦酸盐是相对较新的产物，可以通过几种合成策略来组装。金属聚集体的核性和结构可以通过多种因素进行调节，包括反应物的化学计量、金属前体的性质和所用膦酸的类型。本综述总结了一些关于铜（II）-、锌（II）-和镉（II）膦酸盐的最新研究工作，特别强调了它们的合成和结构。
