Department of Trace Element Analysis by Spectroscopy Method, Faculty of Chemistry, Adam Mickiewicz University, 6 Grunwaldzka Street, Poznan, Poland.
Talanta. 2011 Apr 15;84(2):247-61. doi: 10.1016/j.talanta.2010.10.065. Epub 2011 Jan 26.
Arsenic composes a danger for human health all over the world as it is responsible for water resources contamination. The toxicity of arsenic depends on its chemical form. However, occurrence of particular arsenic species is dependent on processes occurring in water. Nowadays, more arsenic species is detected and analyzed in different kind of water (mineral, tap, waste), mainly owing to great possibilities resulting from coupling high performance liquid chromatography (HPLC) with inductively coupled plasma mass spectrometry (ICP-MS). This review mainly describes arsenic speciation analysis by HPLC-ICP-MS technique on the basis of articles that have been published since 2000. Arsenic chemistry, occurrence in different kind of water, total arsenic determination with interferences elimination and its validation and analytical performance are also reviewed.
砷在全世界范围内构成了对人类健康的威胁，因为它会导致水资源污染。砷的毒性取决于其化学形态。然而，特定砷形态的出现取决于水中发生的过程。如今，在不同类型的水中（矿泉水、自来水、废水）检测和分析到更多的砷形态，主要是由于高效液相色谱（HPLC）与电感耦合等离子体质谱（ICP-MS）联用所带来的巨大可能性。本综述主要描述了自 2000 年以来发表的文章中基于 HPLC-ICP-MS 技术的砷形态分析。还综述了砷化学、不同类型水中的存在、总砷的测定及其干扰消除和验证以及分析性能。
