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Enantiodifferentiating endo-selective oxylactonization of ortho-alk-1-enylbenzoate with a lactate-derived aryl-λ3-iodane.
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Highly enantioselective intramolecular aza-spiroannulation onto indoles using chiral rhodium catalysis: asymmetric entry to the spiro-beta-lactam core of chartellines.
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An expedient route to a potent gastrin/CCK-B receptor antagonist (+)-AG-041R.
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Synthesis of (-)-hygromycin A: application of Mitsunobu glycosylation and tethered aminohydroxylation.
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Total synthesis of the beta-catenin inhibitor, (-)-agelastatin A: a second-generation approach based on radical aminobromination.
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Metal-free oxidative cyclization of urea-tethered alkenes with hypervalent iodine.
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N-tosyloxycarbamates as reagents in rhodium-catalyzed C-H amination reactions.
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Copper-catalyzed alkene aziridination with N-tosyloxycarbamates.
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Copper-catalyzed tethered aziridination of unsaturated N-tosyloxy carbamates.
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