Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871.
Chem Soc Rev. 2011 May;40(5):2435-52. doi: 10.1039/c0cs00129e. Epub 2011 Mar 8.
Carbon dioxide is an important carbon source in the atmosphere and is "problematic" toward the activities of human beings. Although carbon dioxide is a cheap, abundant and relatively nontoxic C1 source, its chemical transformations have not been widely developed so far and are still far from synthetic applications, especially in the construction of the C-C bond. This critical review summarizes the recent advances on transition-metal-catalyzed C-C bond formation through the fixation of carbon dioxide and their synthetic applications (124 references).
二氧化碳是大气中的一种重要碳源，对人类活动来说是“有问题的”。尽管二氧化碳是一种廉价、丰富且相对无毒的 C1 源，但迄今为止，其化学转化尚未得到广泛发展，离合成应用还很远，尤其是在构建 C-C 键方面。这篇评论总结了通过固定二氧化碳实现的过渡金属催化 C-C 键形成及其合成应用的最新进展（124 篇参考文献）。
