通过C（sp）-X键官能化将一氧化碳固定为有用的芳香羧酸。
CO Fixation into Useful Aromatic Carboxylic Acids via C (sp)-X Bonds Functionalization.
作者信息
Chen Youwen, Chen Meihua, Li Xinyu, Xu Xinhua, Yin Shuang-Feng, Qiu Renhua
机构信息
College of Chemistry and Chemical Engineering, Hunan University, Changsha, 4100825, People's Republic of China.
School of Information and Mechanical Engineering, Hunan International Economics University, Changsha, China.
出版信息
Top Curr Chem (Cham). 2025 Mar 3;383(1):11. doi: 10.1007/s41061-025-00496-x.
Carbon dioxide (CO) is an abundant and readily available carbon source. Its transformation into high-added-value chemicals is a beneficial strategy, which mitigates greenhouse gas emissions and provides new raw material sources for the chemical industry. Among these chemicals, the aromatic carboxylic acids and derivatives have broad applications in medicine, pesticides, and materials science. Therefore, the carboxylation of C(sp)-X (X = metal, halide, H, O, or S) bonds with CO to efficiently construct aromatic carboxylic acids and their derivatives is a synthetic strategy of significance. This review highlights the recent progress in constructing carboxylic acids and derivatives through the carboxylation of C(sp)-X bonds with CO including literature published from 2000 to December 2024.
二氧化碳（CO₂）是一种丰富且易于获取的碳源。将其转化为高附加值化学品是一种有益的策略，既能减少温室气体排放，又能为化学工业提供新的原料来源。在这些化学品中，芳香羧酸及其衍生物在医药、农药和材料科学领域有着广泛的应用。因此，通过C(sp)–X（X = 金属、卤化物、氢、氧或硫）键与CO₂进行羧基化反应以高效构建芳香羧酸及其衍生物是一种具有重要意义的合成策略。本综述重点介绍了自2000年至2024年12月期间发表的文献中，通过C(sp)–X键与CO₂进行羧基化反应构建羧酸及其衍生物方面的最新进展。
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