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具有 TiO2 颗粒涂层的仿蛾眼表面的减反射和自清洁性能。

Antireflection and self-cleaning properties of a moth-eye-like surface coated with TiO2 particles.

机构信息

Photocatalyst Group, KSP Building East 412, Kanagawa Academy of Science and Technology, 3-2-1 Sakado, Takatsu-ku, Kawasaki, Kanagawa 213-0012, Japan.

出版信息

Langmuir. 2011 Apr 5;27(7):3275-8. doi: 10.1021/la200438p. Epub 2011 Mar 10.

Abstract

Poly(ethylene terephthalate) (PET) films with a moth-eye-like surface are coated with TiO(2) particles to form self-cleaning antireflective films. The use of a TiO(2) suspension of high concentration to coat the PET surface produces a thicker TiO(2) layer with smaller pores, whereas a low concentration of a TiO(2) suspension gives a thinner layer of TiO(2) with larger pores. The PET films coated with TiO(2) particles exhibit a high transmittance of 76-95% and almost no absorption in the range of 400-800 nm. The PET films coated with a TiO(2) suspension with a concentration of ≥2 vol % exhibit superhydrophilicity after irradiation with UV light. After irradiation, the superhydrophilic nature is retained for at least 18 days. The TiO(2)-coated PET films showed the ability to decompose methylene blue under UV irradiation.

摘要

聚对苯二甲酸乙二醇酯(PET)具有仿蛾眼表面的薄膜涂覆二氧化钛(TiO 2 )颗粒,形成自清洁减反射薄膜。使用高浓度的 TiO 2 悬浮液涂覆 PET 表面会产生更厚的 TiO 2 层,其孔径更小,而 TiO 2 悬浮液的低浓度则会产生更薄的 TiO 2 层,其孔径更大。涂覆 TiO 2 颗粒的 PET 薄膜在 400-800nm 范围内表现出 76-95%的高透过率和几乎没有吸收。浓度≥2vol%的 TiO 2 悬浮液涂覆的 PET 薄膜在紫外线照射后表现出超亲水性。照射后,超亲水性至少保持 18 天。涂覆 TiO 2 的 PET 薄膜在紫外线照射下显示出分解亚甲基蓝的能力。

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