3-乙烯基向 3-甲酰基叶绿素衍生物的温和转化。
A mild conversion from 3-vinyl- to 3-formyl-chlorophyll derivatives.
机构信息
Department of Material and Environmental Chemistry, Graduate School of Engineering, Utsunomiya University, Utsunomiya, Tochigi 321-8585, Japan.
出版信息
Bioorg Med Chem Lett. 2011 Apr 15;21(8):2489-91. doi: 10.1016/j.bmcl.2011.02.054. Epub 2011 Feb 17.
PMID:21392989
Abstract
The C3-vinyl group of a chlorophyll derivative, methyl pyropheophorbide-a, was converted into the formyl group by a novel one-pot reaction with thiophenol at room temperature. The mild reaction can provide insight into development of 'green' catalysts displacing OsO(4) or O(3), and into elucidation of unknown biosynthetic processes of chlorophyll-d.
摘要
叶绿素衍生物甲基脱镁叶绿酸-a 的 C3-乙烯基在室温下与噻酚通过新颖的一锅法反应转化为甲酰基。温和的反应可以为开发替代 OsO(4) 或 O(3) 的“绿色”催化剂以及阐明叶绿素-d 的未知生物合成过程提供思路。
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