铜介导的二甲基亚砜与芳基卤化物的甲基硫代反应。
Copper-mediated methylthiolation of aryl halides with DMSO.
机构信息
College of Chemistry & Materials Engineering, Wenzhou University, Wenzhou 325000, People's Republic of China.
出版信息
Chem Commun (Camb). 2011 May 14;47(18):5304-6. doi: 10.1039/c1cc10795j. Epub 2011 Mar 31.
PMID:21451874
Abstract
A copper-mediated methylthiolation of aryl halides with the widely available DMSO is described. The procedure tolerates a series of functional groups such as methoxy, nitro, chloro, fluoro, trifluoromethyl, formyl and methoxycarbonyl groups. Thus, it represents a simple and facile methylthiolation procedure.
摘要
本文描述了一种使用广泛易得的 DMSO 实现的芳基卤化物的铜介导的甲基化硫代反应。该反应能够容忍一系列官能团，如甲氧基、硝基、氯、氟、三氟甲基、甲酰基和甲氧羰基。因此，它代表了一种简单易行的甲基硫代反应方法。
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