Department of Chemistry, National Dong Hwa University, Hualien, Taiwan 97401, ROC.
Chem Commun (Camb). 2011 May 28;47(20):5831-3. doi: 10.1039/c1cc10168d. Epub 2011 Apr 12.
The first elemental cluster with hexacapped trigonal bipyramidal geometry is revealed in the luminescent undecanuclear silver complex which is stabilized by nine dithiocarbamate ligands and has an interstitial hydride. The hydride position within the Ag(11) cage is confirmed by a DFT investigation.
首个具有六帽三角双锥几何形状的元素簇在发光的十一核银配合物中被揭示出来，该配合物由九个二硫代氨基甲酸盐配体稳定，并具有间隙氢化物。通过 DFT 研究证实了氢化物在 Ag(11)笼内的位置。
