State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, People's Republic of China.
Langmuir. 2011 May 17;27(10):5814-23. doi: 10.1021/la2002018. Epub 2011 Apr 13.
A structure parameter, Sn = η(c)γ/τ(E), is proposed to represent the increase of effective viscosity due to the introduction of particles into a viscous liquid and to analyze the shear behavior of electrorheological (ER) fluids. Sn can divide the shear curves of ER fluids, τ/E(2) versus Sn, into three regimes, with two critical values Sn(c) of about 10(-4) and 10(-2), respectively. The two critical Sn(c) are applicable to ER fluids with different particle volume fractions φ in a wide range of shear rate γ and electric field E. When Sn < 10(-4), the shear behavior of ER fluids is mainly dominated by E and by shear rate when Sn > 10(-2). The electric current of ER fluids under E varied with shear stress in the same or the opposite trend in different shear rate ranges. Sn(c) also separates the conductivity variation of ER fluids into three regimes, corresponding to different structure evolutions. The change of Sn with particle volume fraction and E has also been discussed. The shear thickening in ER fluids can be characterized by Sn(c)(L) and Sn(c)(H) with a critical value about 10(-6). As an analogy to friction, the correspondence between τ/E(2) and friction coefficient, Sn and bearing numbers, as well as the similarity between the shear curve of ER fluids and the Stribeck curve of friction, indicate a possible friction origin in ER effect.
提出了一个结构参数 Sn = η(c)γ/τ(E),用于表示颗粒引入粘性液体中有效粘度的增加,并分析电流变(ER)流体的剪切行为。Sn 可以将 ER 流体的剪切曲线 τ/E(2)与 Sn 划分为三个区域,分别有两个临界值 Sn(c),约为 10(-4)和 10(-2)。这两个临界 Sn(c)适用于在很宽的剪切速率 γ 和电场 E 范围内具有不同颗粒体积分数 φ 的 ER 流体。当 Sn < 10(-4)时,ER 流体的剪切行为主要由 E 和剪切速率决定,当 Sn > 10(-2)时则主要由剪切速率决定。在不同的剪切速率范围内,ER 流体在 E 下的电流与剪切应力呈相同或相反的趋势变化。Sn(c)还将 ER 流体的电导率变化分为三个区域,对应于不同的结构演变。还讨论了 Sn 随颗粒体积分数和 E 的变化。ER 流体的剪切增稠可以用 Sn(c)(L)和 Sn(c)(H)来表征,临界值约为 10(-6)。类似于摩擦,τ/E(2)与摩擦系数、Sn 与承载数之间的对应关系,以及 ER 流体剪切曲线与摩擦的 Stribeck 曲线之间的相似性,表明 ER 效应中可能存在摩擦起源。