Silva Lurdes I B, Justino Celine I L, Lopes Isabel, Pereira Ruth, Freitas Ana Cristina, Calado Ricardo, Rocha-Santos Teresa A P, Panteleitchouk Teresa S L, Pereira Maria E, Duarte Armando Costa
CESAM & Department of Chemistry, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, Portugal.
J Environ Monit. 2011 Jun;13(6):1811-5. doi: 10.1039/c1em10043b. Epub 2011 Apr 15.
A new methodology for the assessment of thiocyanate (SCN(-)) is proposed based on optical fiber (OF) detection coupled to a liquid chromatography system (LC). The developed methodology showed an adequate performance for the analysis of SCN(-) comparable to a high performance liquid chromatography with UV detector (HPLC-UV) methodology: a detection limit of 3 µg L(-1), a linear range from 4 to 400 µg L(-1), and an analytical time of less than 6 min. The OF based methodology was of compact design and easy operation. This simple system has the potential to be used as a sensing approach for SCN(-) in seawater.
提出了一种基于光纤（OF）检测与液相色谱系统（LC）联用的硫氰酸盐（SCN(-)）评估新方法。所开发的方法在分析SCN(-)方面表现出与配备紫外检测器的高效液相色谱（HPLC-UV）方法相当的性能：检测限为3 µg L(-1)，线性范围为4至400 µg L(-1)，分析时间小于6分钟。基于光纤的方法设计紧凑且操作简便。这种简单的系统有潜力用作海水中SCN(-)的传感方法。
