Spivey Alan C, Arseniyadis Stellios
Department of Chemistry, South Kensington Campus, Imperial College, London, SW7 2AZ, UK.
Top Curr Chem. 2010;291:233-80. doi: 10.1007/978-3-642-02815-1_25.
An overview of the area of organocatalytic asymmetric acyl transfer processes is presented including O- and N-acylation. The material has been ordered according to the structural class of catalyst employed rather than reaction type with the intention to draw mechanistic parallels between the manner in which the various reactions are accelerated by the catalysts and the concepts employed to control transfer of chiral information from the catalyst to the substrates.
本文概述了有机催化不对称酰基转移反应领域，包括O-酰化和N-酰化。材料是根据所用催化剂的结构类别而非反应类型进行编排的，目的是在各种反应被催化剂加速的方式与用于控制手性信息从催化剂转移到底物的概念之间建立机理上的相似性。
