Department of Applied Chemistry, China Agricultural University, Beijing 100193, China.
Chem Commun (Camb). 2013 Jul 14;49(55):6131-3. doi: 10.1039/c3cc42669f.
A bidentate iridium NHC-phosphine complex has been developed and applied to the N-monoalkylation of aromatic amines with a wide range of primary alcohols and to the N-heterocyclization of amino alcohols. This reaction resulted in high isolated product yields, even at room temperature and under solvent-free conditions.
一种双齿铱 NHC-膦配合物已被开发出来，并应用于芳香胺与各种伯醇的 N-单烷基化反应，以及氨基醇的 N-杂环化反应。即使在室温下且无溶剂条件下，该反应也能获得高产率的分离产物。
