N,N'-二苄基-N''-(2-氯-2,2-二氟乙酰基)-N,N'-二甲基磷酰胺
N,N'-Dibenzyl-N''-(2-chloro-2,2-difluoro-acet-yl)-N,N'-dimethyl-phospho-ric triamide.
作者信息
Raissi Shabari Akbar, Pourayoubi Mehrdad, Saneei Anahid
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 19;67(Pt 3):o663-4. doi: 10.1107/S1600536811005423.
Abstract
In the title mol-ecule, C(18)H(21)ClF(2)N(3)O(2)P, the P=O and N-H groups are syn to each other. The P atom adopts a slightly distorted tetra-hedral environment and the N atoms of the tertiary amine groups are bonded in an essentially planar geometry. In the crystal, pairs of inter-molecular N-H⋯O(P) hydrogen bonds form centrosymmetric dimers.
摘要
在标题分子C(18)H(21)ClF(2)N(3)O(2)P中，P=O和N-H基团彼此顺式排列。P原子处于略微扭曲的四面体环境中，叔胺基团的N原子以基本平面的几何构型键合。在晶体中，分子间的N-H⋯O(P)氢键对形成中心对称二聚体。
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本文引用的文献
1
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Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 13;66(Pt 2):o344. doi: 10.1107/S1600536810000851.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
A Novel Optical Complex between an Organic Substrate and a Polyoxometalate. Crystal and Molecular Structure of alpha-H(4)SiW(12)O(40).4HMPA.2H(2)O (HMPA = Hexamethylphosphoramide).一种有机底物与多金属氧酸盐之间的新型光学配合物。α-H(4)SiW(12)O(40).4HMPA.2H(2)O（HMPA = 六甲基磷酰胺）的晶体和分子结构
Inorg Chem. 1996 Jul 3;35(14):4211-4217. doi: 10.1021/ic951458i.
4
Graph-set analysis of hydrogen-bond patterns in organic crystals.有机晶体中氢键模式的图形集分析。
Acta Crystallogr B. 1990 Apr 1;46 ( Pt 2):256-62. doi: 10.1107/s0108768189012929.
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