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N,N'-二苄基-N''-(2-氯-2,2-二氟乙酰基)-N,N'-二甲基磷酰胺

N,N'-Dibenzyl-N''-(2-chloro-2,2-difluoro-acet-yl)-N,N'-dimethyl-phospho-ric triamide.

作者信息

Raissi Shabari Akbar, Pourayoubi Mehrdad, Saneei Anahid

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 19;67(Pt 3):o663-4. doi: 10.1107/S1600536811005423.

DOI:10.1107/S1600536811005423
PMID:21522414
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3052170/
Abstract

In the title mol-ecule, C(18)H(21)ClF(2)N(3)O(2)P, the P=O and N-H groups are syn to each other. The P atom adopts a slightly distorted tetra-hedral environment and the N atoms of the tertiary amine groups are bonded in an essentially planar geometry. In the crystal, pairs of inter-molecular N-H⋯O(P) hydrogen bonds form centrosymmetric dimers.

摘要

在标题分子C(18)H(21)ClF(2)N(3)O(2)P中，P=O和N-H基团彼此顺式排列。P原子处于略微扭曲的四面体环境中，叔胺基团的N原子以基本平面的几何构型键合。在晶体中，分子间的N-H⋯O(P)氢键对形成中心对称二聚体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68b8/3052170/851d1a4bd2f8/e-67-0o663-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68b8/3052170/a1039a212f5a/e-67-0o663-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68b8/3052170/851d1a4bd2f8/e-67-0o663-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68b8/3052170/a1039a212f5a/e-67-0o663-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68b8/3052170/851d1a4bd2f8/e-67-0o663-fig2.jpg

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N,N'-Dibenzyl-N''-(2-chloro-2,2-difluoro-acet-yl)phospho-ric triamide.N,N'-二苄基-N''-(2-氯-2,2-二氟乙酰基)磷酰三胺
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N,N'-Dicyclo-hexyl-N''-(4-nitro-benzo-yl)phospho-ric triamide.
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