N,N,N',N'-四苄基-N''-(2,6-二氟苯甲酰基)磷酰三酰胺
N,N,N',N'-Tetra-benzyl-N''-(2,6-difluoro-benzo-yl)phospho-ric triamide.
作者信息
Raissi Shabari Akbar, Pourayoubi Mehrdad, Tarahhomi Atekeh, Rheingold Arnold L, Golen James A
机构信息
Faculty of Chemistry, North Tehran Branch, Islamic Azad University, Tehran, Iran.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):o3186. doi: 10.1107/S1600536812042481. Epub 2012 Oct 20.
In the C(O)NHP(O) fragment of the title compound, C(35)H(32)F(2)N(3)O(2)P, the P-N bond is longer and the O-P-N angle is contracted compared with the other two P-N bonds and O-P-N angles. The P atom adopts a distorted tetra-hedral environment and the phosphoryl and carbonyl groups are anti with respect to each other. The two tertiary N atoms of the dibenzyl-amido groups show sp(2) character with a slight deviation from planarity. In the crystal, pairs of N-H⋯O(P) hydrogen bonds form inversion dimers.
在标题化合物C(35)H(32)F(2)N(3)O(2)P的C(O)NHP(O)片段中，与其他两个P-N键和O-P-N角相比，P-N键更长，O-P-N角收缩。P原子采用扭曲的四面体环境，磷酰基和羰基相互呈反式。二苄基酰胺基的两个叔氮原子表现出sp(2)特征，与平面有轻微偏差。在晶体中，N-H⋯O(P)氢键对形成反转二聚体。
Zotero 插件