Abdelhamid Antar A, Mohamed Shaaban K, Khalilov Ali N, Gurbanov Atash V, Ng Seik Weng
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 26;67(Pt 3):o744. doi: 10.1107/S1600536811006969.
The dihydro-pyridine ring in the title compound, C(25)H(31)NO(4), adopts an envelope conformation with the methine C atom representing the flap. The cyclo-hexenone rings also adopt envelope conformations with the C atoms bearing the methyl C atoms representing the flaps. The phenolic hy-droxy group forms an intra-molecular hydrogen bond to one of the two keto O atoms. The hy-droxy group of the N-bonded alkyl chain forms an inter-molecular hydrogen bond to the other keto O atom of an adjacent mol-ecule. The latter hydrogen bond leads to the formation of a helical chain running along the b axis.
标题化合物C(25)H(31)NO(4)中的二氢吡啶环呈信封式构象,次甲基C原子为折叶。环己烯酮环也呈信封式构象,带有甲基C原子的C原子为折叶。酚羟基与两个酮O原子之一形成分子内氢键。N键合烷基链的羟基与相邻分子的另一个酮O原子形成分子间氢键。后一种氢键导致沿b轴形成螺旋链。