Meyer Nadine, Mohr Fabian, Tiekink Edward R T
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 16;66(Pt 2):m168-9. doi: 10.1107/S1600536810001418.
In the title mixed solvate, [Au(2)Fe(C(17)H(14)P)(2)Cl(2)]·CHCl(3)·0.5CH(3)(CH(2))(4)CH(3), the hexane solvent mol-ecule is disposed about an inversion centre. The Au atoms exist within nearly ideal linear coordination defined by P,Cl-donor sets, and when viewed down the P⋯P axis the Au atoms are gauche to each other. In the crystal structure, the chloro-form solvent mol-ecule is associated with the complex via a C-H⋯Cl contact, and the hexane solvent mol-ecules occupy voids defined by the remaining components of the structure.
在标题配合物[Au₂Fe(C₁₇H₁₄P)₂Cl₂]·CHCl₃·0.5CH₃(CH₂)₄CH₃中，己烷溶剂分子位于一个对称中心上。金原子存在于由磷和氯供体基团定义的近乎理想的线性配位环境中，当沿P⋯P轴向下看时，金原子彼此呈gauche构象。在晶体结构中，氯仿溶剂分子通过C-H⋯Cl接触与配合物相连，己烷溶剂分子占据由结构中其余部分所定义的空隙。
