叠氮基-[1,2-双-(二苯基膦基)乙烷-κP,P'](η-茚基)钌(II)
Azido-[1,2-bis-(diphenyl-phosphan-yl)ethane-κP,P'](η-inden-yl)ruthenium(II).
作者信息
Sung Hui-Ling, Hsu Hsiu-Ling, Kuo Ting-Shen
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 24;67(Pt 1):m124. doi: 10.1107/S1600536810053006.
Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η(5)-C(9)H(7))Cl(dppe)] (dppe is diphenylphosphanyl ethane) is treated with NaN(3) in refluxing ethanol, yielding the title compound, [Ru(η(5)-C(9)H(7))(N(3))(dppe)] or [Ru(C(9)H(7))(N(3))(C(26)H(24)P(2))]. The Ru(II) atom has a typical piano-stool coordination. The Ru-P bond lengths are 2.284 (2) and 2.235 (2) Å. NMR and MS analyses are in agreement with the structure of the title compound.
当氯化钌配合物[Ru(η(5)-C(9)H(7))Cl(dppe)]（dppe为二苯基膦基乙烷）在回流乙醇中用NaN(3)处理时，观察到容易发生配体取代反应，生成标题化合物[Ru(η(5)-C(9)H(7))(N(3))(dppe)]或[Ru(C(9)H(7))(N(3))(C(26)H(24)P(2))]。Ru(II)原子具有典型的钢琴凳式配位结构。Ru-P键长分别为2.284 (2) Å和2.235 (2) Å。核磁共振（NMR）和质谱（MS）分析结果与标题化合物的结构相符。
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