氯（氯代二苯基膦-κP）（二苯基哌啶膦-κP）（η-五甲基环戊二烯基）钌（II）
Chlorido(chloro-diphenyl-phosphine-κP)(diphenyl-piperidinophosphine-κP)(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(II).
作者信息
Jantscher Florian, Kirchner Karl, Mereiter Kurt
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 18;65(Pt 8):m941. doi: 10.1107/S1600536809027676.
Abstract
The title compound, [Ru(C(10)H(15))Cl(C(12)H(10)ClP)(C(17)H(20)NP)], is a half-sandwich complex of Ru(II) with the chloro-diphenyl-phosphine ligand formed from the diphenyl-piperidinophosphine and chlorine of the precursor complex [Ru(η(5)-C(5)Me(5))(κ(1)P-Ph(2)PNC(5)H(10))Cl(2)] by an unexpected reaction with NaBH(4). The complex has a three-legged piano-stool geometry, with Ru-P bond lengths of 2.2598 (5) Å for the chloro-phosphine and 2.3303 (5) Å for the amino-phosphine.
摘要
标题化合物[Ru(C₁₀H₁₅)Cl(C₁₂H₁₀ClP)(C₁₇H₂₀NP)]是Ru(II)的半夹心配合物，其氯代二苯基膦配体由二苯基哌啶膦与前体配合物[Ru(η⁵-C₅Me₅)(κ¹P-Ph₂PNC₅H₁₀)Cl₂]中的氯通过与NaBH₄的意外反应形成。该配合物具有三脚钢琴凳几何构型，氯代膦的Ru-P键长为2.2598 (5) Å，氨基膦的Ru-P键长为2.3303 (5) Å。
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