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顺式-二氯四（三甲基膦-κP）钌（II）苯二溶剂合物

cis-Dichloridotetra-kis-(trimethyl-phosphane-κP)ruthenium(II) benzene disolvate.

作者信息

Fu Chen, Wen Ting Bin

机构信息

Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 4;67(Pt 1):m14. doi: 10.1107/S1600536810049706.

DOI:10.1107/S1600536810049706
PMID:21522541
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3050259/
Abstract

The title compound, cis-[RuCl(2)(C(3)H(9)P)(4)]·2C(6)H(6), contains a complex mol-ecule with a crystallographic mirror plane passing through the Ru(II) atom, the two cis-disposed Cl ligands and two P atoms of the two cis-disposed P(CH(3))(3) ligands. The Ru(II) atom adopts a distorted octa-hedral RuCl(2)P(4) coordination geometry with the two trans-disposed P atoms occupying the axial positions. The packing of the structure is accomplished through non-classical C-H⋯Cl hydrogen bonds between the benzene solvent mol-ecule and one of the Cl ligands.

摘要

标题化合物顺式 - [RuCl₂(C₃H₉P)₄]·2C₆H₆包含一个复杂分子，该分子具有一个通过Ru(II)原子、两个顺式排列的Cl配体以及两个顺式排列的P(CH₃)₃配体中的两个P原子的晶体学镜面。Ru(II)原子采用扭曲的八面体RuCl₂P₄配位几何结构，两个反式排列的P原子占据轴向位置。结构的堆积是通过苯溶剂分子与其中一个Cl配体之间的非经典C - H⋯Cl氢键实现的。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0ba7/3050259/dfcc8853496e/e-67-00m14-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0ba7/3050259/0c1890f0c050/e-67-00m14-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0ba7/3050259/dfcc8853496e/e-67-00m14-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0ba7/3050259/0c1890f0c050/e-67-00m14-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0ba7/3050259/dfcc8853496e/e-67-00m14-fig2.jpg

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本文引用的文献

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