Bats Jan W, Pérez Gomes Jessica, Doppiu Angelino, Hashmi A Stephen K
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m723-4. doi: 10.1107/S1600536811016692. Epub 2011 May 7.
The Ru(II) atom in the title compound, [RuCl(2)(C(15)H(10))(C(18)H(15)P)(2)]·2C(4)H(8)O, has a distorted square-pyramidal conformation. The P and Cl atoms are at the base of the pyramid and the Ru-C(indenyl-idene) bond is in the axial position. The two Cl ligands and the two phosphane ligands are in trans positions. The Cl-Ru-Cl and P-Ru-P angles are 157.71 (2) and 166.83 (2)°, respectively. The two independent tetra-hydro-furan (THF) solvent mol-ecules are disordered. One THF mol-ecule was refined using a split-atom model. The second THF mol-ecule was accounted for by using program PLATON/SQUEEZE [Spek (2009 ▶). Acta Cryst. D65, 148-155]. The molecular conformation shows three intramolecular C-H⋯Cl contacts and two C-H⋯π interactions while the crystal packing features an intermolecular C-H⋯Cl contact and two very weak intermolecular C-H⋯π contacts.
标题化合物[RuCl₂(C₁₅H₁₀)(C₁₈H₁₅P)₂]·2C₄H₈O中的Ru(II)原子具有扭曲的四方锥构象。P和Cl原子位于锥底，Ru-C(茚基亚甲基)键处于轴向位置。两个Cl配体和两个膦配体处于反式位置。Cl-Ru-Cl和P-Ru-P角分别为157.71 (2)°和166.83 (2)°。两个独立的四氢呋喃(THF)溶剂分子是无序的。一个THF分子用分裂原子模型进行精修。第二个THF分子用PLATON/SQUEEZE程序[Spek (2009 ▶). Acta Cryst. D65, 148 - 155]处理。分子构象显示有三个分子内C-H⋯Cl接触和两个C-H⋯π相互作用，而晶体堆积具有一个分子间C-H⋯Cl接触和两个非常弱的分子间C-H⋯π接触。
