二-μ-氯-双-({2-[(4-溴-苯基)-亚氨基-甲基]吡啶-κN,N'}-氯化汞(II))
Di-μ-chlorido-bis-({2-[(4-bromo-phen-yl)-imino-meth-yl]pyridine-κN,N'}-chloridomercury(II)).
作者信息
Mahmoudi Ali, Dehghanpour Saeed, Khalaj Mehdi, Pakravan Shabnam
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m889. doi: 10.1107/S1600536809025641.
Abstract
The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.
摘要
在标题中心对称双核配合物[Hg₂Cl₄(C₁₂H₉BrN₂)₂]中，独特的Hg(II)离子处于由双螯合N-杂环配体、两个桥连Cl原子和一个端基Cl原子形成的扭曲三角双锥配位环境中。其中一个桥连Hg-Cl键明显比另一个长。
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