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二-μ-氯-双-({2-[(4-溴-苯基)-亚氨基-甲基]吡啶-κN,N'}-氯化汞(II))

Di-μ-chlorido-bis-({2-[(4-bromo-phen-yl)-imino-meth-yl]pyridine-κN,N'}-chloridomercury(II)).

作者信息

Mahmoudi Ali, Dehghanpour Saeed, Khalaj Mehdi, Pakravan Shabnam

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m889. doi: 10.1107/S1600536809025641.

DOI:10.1107/S1600536809025641
PMID:21583352
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977257/
Abstract

The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.

摘要

在标题中心对称双核配合物[Hg₂Cl₄(C₁₂H₉BrN₂)₂]中，独特的Hg(II)离子处于由双螯合N-杂环配体、两个桥连Cl原子和一个端基Cl原子形成的扭曲三角双锥配位环境中。其中一个桥连Hg-Cl键明显比另一个长。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2bb6/2977257/e372a7031990/e-65-0m889-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2bb6/2977257/e372a7031990/e-65-0m889-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2bb6/2977257/e372a7031990/e-65-0m889-fig1.jpg

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2
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
3
A short history of SHELX.SHELX简史。
2-[1-(3-{2-[(2-Hy-droxy-benzyl-idene)amino]-phen-oxy}prop-yl)-1H-1,3-benzodiazol-2-yl]phenol.
2-[1-(3-{2-[(2-羟基苯亚甲基)氨基]苯氧基}丙基)-1H-1,3-苯并二唑-2-基]苯酚
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 19;67(Pt 3):o657-8. doi: 10.1107/S1600536811005319.
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Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 12;67(Pt 3):m327. doi: 10.1107/S1600536811004703.
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.