二氯{2-吗啉代-N-[1-(2-吡啶基)亚乙基]乙胺-κN,N',N''}锌(II)
Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).
作者信息
Ikmal Hisham Nurul Azimah, Suleiman Gwaram Nura, Khaledi Hamid, Mohd Ali Hapipah
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 11;67(Pt 1):m55. doi: 10.1107/S1600536810050671.
In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N',N''-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intra-molecular C-H⋯Cl inter-action occurs. In the crystal, adjacent mol-ecules are linked together via C-H⋯Cl hydrogen-bonding and long range C-H⋯O and C-H⋯Cl inter-actions into a three-dimensional network.
在标题化合物[ZnCl₂(C₁₃H₁₉N₃O)]中，席夫碱配体作为一种N,N',N''-三齿螯合剂，与Zn(II)离子形成两个五元环。金属原子通过席夫碱配体和两个Cl原子以扭曲的四方锥几何构型进行五配位。存在分子内C—H⋯Cl相互作用。在晶体中，相邻分子通过C—H⋯Cl氢键以及长程C—H⋯O和C—H⋯Cl相互作用连接在一起，形成三维网络。
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