氯代[1-(4,5-二氢-1,3-噻唑-2-基-κN)乙酮硫代半卡巴腙合-κN,S]镍(II)
Chlorido[1-(4,5-dihydro-1,3-thia-zol-2-yl-κN)ethanone thio-semicarbazonato-κN,S]nickel(II).
作者信息
Viñuelas-Zahínos Emilio, Luna-Giles Francisco, Torres-García Pablo, Bernalte-García Alvaro
机构信息
Departamento de Quimica Organica e Inorganica, Facultad de Ciencias, Universidad de Extremadura, Badajoz, Spain.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 15;67(Pt 1):m79. doi: 10.1107/S1600536810051500.
Abstract
In the title compound, [Ni(C(6)H(9)N(4)S(2))Cl], the Ni atom is in a slightly distorted square-planar environment coordinated by a Cl atom and a deprotonated thio-semicarbazone ligand via its thia-zoline N, azomethine N and thiol-ate S atoms. Short inter-molecular N-H⋯Cl and C-H⋯S contacts are present in the crystal structure.
摘要
在标题化合物[Ni(C₆H₉N₄S₂)Cl]中，镍原子处于略微扭曲的平面正方形环境中，由一个氯原子和一个去质子化的硫代半卡巴腙配体通过其噻唑啉氮原子、偶氮甲碱氮原子和硫醇盐硫原子配位。晶体结构中存在短的分子间N—H⋯Cl和C—H⋯S接触。
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