（3,5-二氯-2-氧化苯甲醛硫代半卡巴腙-κS,N,O）（甲醇-κO）（1,10-菲啰啉-κN,N'）镍（II）
mer-(3,5-Dichloro-2-oxidobenzaldehyde thio-semicarbazonato-κS,N,O)(methanol-κO)(1,10-phenanthroline-κN,N')nickel(II).
作者信息
Gao J Y, Liu Z, Wang Y
机构信息
Key Laboratory of Non-ferrous Metal Materials and Processing Technology, Department of Material and Chemical Engineering, Guilin University of Technology, Ministry of Education, Guilin 541004, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 18;65(Pt 5):m523-4. doi: 10.1107/S1600536809013208.
In the title compound, [Ni(C(8)H(5)Cl(2)N(3)OS)(C(12)H(8)N(2))(CH(3)OH)], the Ni(II) atom is octa-hedrally coordinated by one N, one O and one S atom from a 3,5-dichloro-2-oxidobenzaldehyde thio-semicarbazonate ligand, another O atom from methanol and another two N atoms from 1,10-phenanthroline. The crystal structure is constructed by N-H⋯Cl, N-H⋯N, C-H⋯S and O-H⋯S hydrogen bonds.
在标题化合物[Ni(C₈H₅Cl₂N₃OS)(C₁₂H₈N₂)(CH₃OH)]中，Ni(II)原子由3,5-二氯-2-氧化苯甲醛硫代半卡巴腙配体中的一个N原子、一个O原子和一个S原子、甲醇中的另一个O原子以及1,10-菲咯啉中的另外两个N原子八面体配位。晶体结构由N-H⋯Cl、N-H⋯N、C-H⋯S和O-H⋯S氢键构成。
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