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链状聚[[[水合氯锰（II）]-双-[μ-1,1'-（对苯二氧基）二-1H-咪唑-κN:N]]氯化物二甲基甲酰胺单溶剂合物一水合物]

catena-Poly[[[aqua-chlorido-manganese(II)]-bis-[μ-1,1'-(oxydi-p-phenyl-ene)di-1H-imidazole-κN:N]] chloride dimethyl-formamide mono-solvate monohydrate].

作者信息

Mu Xiao-Long

机构信息

College of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 15;67(Pt 2):m166-7. doi: 10.1107/S1600536810054383.

DOI:10.1107/S1600536810054383
PMID:21522845
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3051568/
Abstract

The title coordination polymer, {[MnCl(C(18)H(14)N(4)O)(2)(H(2)O)]Cl·C(3)H(7)NO·H(2)O}(n), obtained by the solvothermal reaction of BIDPE and manganese(II) salt in H(2)O/DMF (DMF is dimethyl-formamide), is composed of a chain of [Mn(2)(BIDPE)(2)] [BIDPE is 1,1'-(oxydi-p-phenyl-ene)di-1H-imidazole] metallocyclic rings that exhibit inversion symmetry. The coordination about the Mn(II) ions is distorted octahedral with a MnClN(4)O coordination set. In the crystal, the polymeric chains are linked by O-H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to (100). A number of C-H⋯Cl and C-H⋯O inter-actions are also present.

摘要

通过BIDPE与锰（II）盐在水/二甲基甲酰胺（DMF）中进行溶剂热反应得到的标题配位聚合物{[MnCl(C₁₈H₁₄N₄O)₂(H₂O)]Cl·C₃H₇NO·H₂O}ₙ，由[Mn₂(BIDPE)₂]链（BIDPE为1,1'-（氧二对亚苯基）二-1H-咪唑）组成的金属环，呈现反演对称性。Mn（II）离子周围的配位为扭曲的八面体，具有MnClN₄O配位集。在晶体中，聚合物链通过O-H⋯Cl氢键连接，形成平行于（100）的二维网络。还存在许多C-H⋯Cl和C-H⋯O相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b9d7/3051568/3b6e7823abb5/e-67-0m166-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b9d7/3051568/036fc1dc5f12/e-67-0m166-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b9d7/3051568/6468e91c725e/e-67-0m166-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b9d7/3051568/3b6e7823abb5/e-67-0m166-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b9d7/3051568/036fc1dc5f12/e-67-0m166-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b9d7/3051568/6468e91c725e/e-67-0m166-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b9d7/3051568/3b6e7823abb5/e-67-0m166-fig3.jpg

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