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3-氯-N'-[(2-羟基萘-1-基)亚甲基]苯甲酰肼

3-Chloro-N'-[(2-hy-droxy-naphthalen-1-yl)methyl-idene]benzohydrazide.

作者信息

Li Tian-Yi, Li Wei

机构信息

School of Chemical Engineering, Changchun University of Technology, Changchun 130012, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 12;67(Pt 2):o373. doi: 10.1107/S1600536811000912.

DOI:10.1107/S1600536811000912
PMID:21523050
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3051679/
Abstract

The title compound, C(18)H(13)ClN(2)O(2), was prepared by the reaction of 2-hy-droxy-1-naphthaldehyde with 3-chloro-benzohydrazide in methanol. An intra-molecular O-H⋯N hydrogen bond influences the mol-ecular conformation; the benzene ring and naphthyl ring system form a dihedral angle of 17.1 (3)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains propagated in [101].

摘要

标题化合物C(18)H(13)ClN(2)O(2)是由2-羟基-1-萘甲醛与3-氯苯甲酰肼在甲醇中反应制备的。分子内O-H⋯N氢键影响分子构象；苯环和萘环体系形成17.1 (3)°的二面角。在晶体中，分子间N-H⋯O氢键将分子连接成沿[101]方向延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1671/3051679/b53ef8af4892/e-67-0o373-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1671/3051679/67a3a39248e6/e-67-0o373-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1671/3051679/b53ef8af4892/e-67-0o373-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1671/3051679/67a3a39248e6/e-67-0o373-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1671/3051679/b53ef8af4892/e-67-0o373-fig2.jpg

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