Li Tian-Yi, Ge Yan-Xia
School of Chemical Engineering, Changchun University of Technology, Changchun 130012, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 12;67(Pt 2):o374. doi: 10.1107/S1600536811000924.
The title compound, C(19)H(15)ClN(2)O(2), was prepared by the reaction of 2-meth-oxy-1-naphthaldehyde with 3-chloro-benzohydrazide in methanol. The dihedral angle between the benzene ring and the naphthyl ring system is 69.0 (3)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains along the c axis. The crystal packing exhibits π-π inter-actions, as indicated by distances of 3.768 (3) Å between the centroids of the naphthyl rings of neighbouring mol-ecules.
标题化合物C(19)H(15)ClN(2)O(2)是通过2-甲氧基-1-萘甲醛与3-氯苯甲酰肼在甲醇中反应制备的。苯环与萘基环系统之间的二面角为69.0 (3)°。在晶体中,分子间的N-H⋯O氢键将分子沿c轴连接成链。如相邻分子萘基环质心之间的距离为3.768 (3) Å所示,晶体堆积呈现π-π相互作用。