Geochemistry and Environment Division, Institute of Chemistry, Jan Kochanowski University, 15G Świętokrzyska St, 25-406 Kielce, Poland.
Environ Int. 2011 Oct;37(7):1265-72. doi: 10.1016/j.envint.2011.04.009. Epub 2011 Apr 30.
Obsolete pesticides were stored in Poland from the middle sixties until the late eighties of the 20th century mostly in underground disposal sites, called "pesticide burial grounds" or "pesticide tombs". The total amount of pesticide waste and packaging materials disposed of in these landfills exceeded 20000 Mg. Typically, the content of a pesticide tomb was dominated by organochlorine pesticides (comprising 10-100% of the total waste volume) with DDT as the prevailing compound. Other pesticide types, such as phosphoroorganic, carbamate insecticides, dinitrophenols, phenoxyacids, and inorganic compounds were stored in smaller quantities, usually not exceeding 10-20% of the total waste volume. With the growing awareness of the threats that these landfills posed to the environment, the first inventory for the whole country was made in 1993 and remediation was initiated in 1999. The total amount of waste, which had to be removed from the known pesticide tombs (hazardous substances, contaminated soils, construction materials etc.) was about 100000 Mg. According to the National Waste Management Plan, the reclamation of pesticide tombs was assumed to have been finished by the end of 2010, however, this goal has not been achieved. The aim of this review is to present a historical perspective of pesticide burial grounds in Poland with an emphasis on their creation, function, inventory, and remediation. Based on unpublished reports, and other published materials of limited availability written in Polish, this review may serve as a source of information for representatives of other countries, where remediation of pesticide burial grounds is still in progress. The experience gained over a ten-year period, when restoration of pesticide tombs was implemented in Poland, reveals that there are many obstacles to this action arising not only from technical, but also from economic and social issues.
废弃农药于 20 世纪 60 年代中期至 80 年代末在波兰主要存放在地下处置场,称为“农药填埋场”或“农药墓地”。这些垃圾填埋场处理的农药废物和包装材料总量超过 20000 公吨。通常,一个农药墓地的主要成分是有机氯农药(占总废物量的 10-100%),以滴滴涕为主要化合物。其他类型的农药,如有机磷、氨基甲酸酯杀虫剂、二硝基苯酚、苯氧羧酸和无机化合物的储存量较小,通常不超过总废物量的 10-20%。随着人们对这些垃圾填埋场对环境构成的威胁的认识不断提高,1993 年对全国进行了第一次清查,并于 1999 年开始进行补救。必须从已知的农药墓地(危险物质、受污染的土壤、建筑材料等)中清除的废物总量约为 100000 公吨。根据国家废物管理计划,到 2010 年底,农药墓地的开垦工作应该已经完成,但这一目标尚未实现。本综述的目的是从历史的角度介绍波兰的农药墓地,重点介绍其创建、功能、清查和补救情况。基于未发表的报告,以及其他有限的、以波兰语发表的可用材料,本综述可作为其他国家的代表的信息来源,这些国家的农药墓地的补救工作仍在进行中。在波兰实施农药墓地修复的十年期间获得的经验表明,这一行动面临着许多障碍,这些障碍不仅来自技术方面,还来自经济和社会方面。